The mitre shows a hairline
If it is under about a millimetre and the same width all the way along, a close-coloured silicone smoothed in one pass finishes it. If it is a wedge — wide at one end, tight at the other — the angle is wrong, not the filling. Take off whatever has not set and re-cut to the angle actually measured.
The wall bows, leaving gaps behind the run
Do not bend the length to follow it. PS is not made to be curved — the material comparison on the home page says so. Let it touch the highest point, put more adhesive only where the wall falls away, and close the top edge with silicone.
The floor is uneven and there is a gap underneath
A gap under the moulding is harder to hide than one above it, because it sits exactly where the eye sweeps. If it runs the whole way, go up one section height and take the gap out. If it is only in places, silicone it in the colour of the floor rather than the colour of the moulding, and the eye reads it as the floor's edge.
One piece has been cut short
Do not push it tight to one side and leave the corner open. On a long run, turn that point into a 45° lap joint and add a second piece — a join along the wall is far less visible than a gap at a corner.
Adhesive on the face
Wipe it with soapy water before it skins. Once dry, do not reach for thinner or a strong cleaner: the wood-grain surface is a film, and solvent bleaches it permanently. Pare it off carefully with a knife instead.
Bathroom or balcony — can it go there?
Yes. The material is waterproof and termites will not eat it. What needs care is the joints: run an unbroken silicone bead along the bottom edge where it meets the floor, so there is no gap for water to sit behind.